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This paper aims to investigate hot corrosion behaviour of different Cr₃C₂–NiCr coatings on boiler tube steel.

High velocity oxy fuel technique has been used to deposit different coatings on commercially available ASTM-SA213-T22 boiler tube steel. The hot corrosion studies have been performed in molten salt environment at 900°C temperature in silicon tube furnace in laboratory.

The results showed that uncoated superalloy suffered intense spalling and the weight change was massive during each cycle on studies of hot corrosion 900°C. The 100 per cent NiCr and 10 per cent (Cr₃C₂) – 90 per cent (NiCr) coatings provided better protection to T22 steel against the hot corrosion because of the formation of Ni and Cr₃C₂ layers.

In this research a variety of coatings have been used. This research work has been aimed to investigate the hot corrosion behavior of Boiler Steel b with different Cr₃C₂–NiCr coatings, under molten salt environment in Silicon tube furnace at 900°C, under cyclic conditions.

This paper aims to investigate the hot corrosion behavior of Ni-Cr and Cr3C2-NiCr coatings, deposited on T11, P91 boiler steels by detonation gun spray coating (D-Gun) process to enhance high temperature corrosion resistance.

Hot corrosion studies were conducted in secondary super heater zone of boiler at 900 °C for 10 cycles on bare and D-Gun coated steel specimens. The microhardness and porosity values of as-sprayed coatings were measured before exposing the specimens in the boiler environment. Each cycle consisted 100 h of heating in the boiler environment followed by 20 min of cooling in air. The weight change measurements were performed after each cycle to establish the kinetics of corrosion using thermogravimetric technique. X-ray diffraction, SEM techniques were used to analyze the corroded specimens.

Uncoated boiler steel experienced higher weight loss. The Cr3C2-NiCr coating was found to be more protective than Ni-Cr coating. The phases revealed the formation of oxide scale on coated specimens, mainly consist of nickel and chromium, which are reported to be protective against the hot corrosion.

There is very limited reported literature on hot corrosion behavior of Ni-Cr and Cr3C2-NiCr coatings deposited on the T11 and P91 substrates by detonation gun (D-gun) spray technique. T11 and P91 alloy steels have been chosen for this study because these two alloys are used to manufacture boiler tubes used in Indian thermal power plants.

This paper aims to use the high-velocity oxy fuel (HVOF) spraying process for depositing 93(WC–Cr₃C₂)–7Ni, 75Cr₃C₂–25NiCr, 83WC–17C_O and 86WC–10C_O–4Cr coatings on ASME SA213 T91 to study the corrosion resistance of these coatings in an actual boiler environment.

The HVOF spraying process was used for depositing 93(WC–Cr₃C₂)–7Ni, 75Cr₃C₂–25NiCr, 83WC–17C_O and 86WC–10C_O–4Cr coatings on ASME SA213 T91. All the coatings obtained are found to be uniform, dense and having thickness between 200 and 250 μm. All the coatings were exposed in an actual boiler environment at 900°C temperature for 10 cycles. Each cycle consisted of 100 h heating followed by 1 h cooling at ambient conditions. X-ray diffraction, scanning electron microscopy and energy-dispersive spectroscopy techniques were used to analyse corrosion products.

All the coated samples were found to be having higher corrosion resistance than the uncoated samples. Among coated specimens, 93(WC–Cr₃C₂)–7Ni coating has shown maximum and 75Cr₃C₂–25NiCr coating has shown minimum resistance to corrosion.

This paper is original research.

This paper aims to evaluate the mechanical properties and slurry erosion behaviour of 10TiO2-Cr2O3 coated turbine steel.

Slurry erosion experiments were performed on the coated turbine steel specimens using slurry erosion test rig under accelerated conditions such as rotational speed, average particle size and slurry concentration. Surface roughness tester, Vickers microhardness tester and scanning electron microscope were used to analyse erosion mechanism.

Under all experimental conditions, 10TiO2-Cr2O3 coated steel showed better slurry erosion resistance in comparison with Al2O3 coated and uncoated steel specimens. Each experimental condition indicated a significant effect on the erosion rate of both coatings and uncoated steel. The surface analysis of uncoated eroded specimen revealed that plastic deformation, ploughing and deep craters formation were the reasons for mass loss, whereas microchipping, ploughing and microcutting were the reasons for mass loss of coated specimens.

The present investigation provides novel insight into the comparative slurry erosion performance of high velocity oxy fuel deposited 10TiO2-Cr2O3 and Cr2O3 coatings under various environmental conditions. To form modified powder, 10 Wt.% TiO2 was added to 90 Wt.% Cr2O3.

Tool steel (AISI D3) is a preferred material for industrial usage. Some of the typical applications of D3 tool steel are blanking and forming dies, forming rolls, press tools and punches bushes. It is used under conditions where high resistance to wear or to abrasion is required and also for resistance to heavy pressure rather than to sudden shock is desirable. It is a high carbon and high chromium steel. Therefore, wire electric discharge machining (WEDM) is used to machine this tool steel. The paper aims to discuss these issues.

The present experimental investigation evaluates the influence of cryogenically treated wires on material removal rate (MRR) and surface roughness (SR) for machining of AISI D3 steel using the WEDM process. Two important process responses MRR and SR have been studied as a function of four different control parameters, namely pulse width, time between two pulses, wire mechanical tension and wire feed rate.

It was found that pulse width was the most significant parameter which affects the MRR and SR. Better surface finish was obtained with cryogenically treated zinc coated wire than brass wire.

The review of the literature indicates that there is limited published work on the effect of machining parameters in WEDM in cryogenic treated wires. Therefore, in this research work, it was decided to evaluate the effect of cryogenically treated wires on WEDM.

The purpose of this study was to fabricate carbon nanotubes (CNT)-reinforced chromium oxide coatings and investigate mechanical and microstructural properties of these newly developed coatings on the boiler tube steel.

1 and 4 Wt.% CNT-reinforced Cr₂O₃ composite coatings were prepared and successfully deposited on ASTM-SA213-T22 (T22) boiler tube steel substrates using high-velocity oxy fuel (HVOF) thermal spraying method. Microhardness, porosity, metallography, X-ray diffraction (XRD), scanning electron microscopy (SEM)/energy-dispersive X-ray spectroscopy, cross-sectional elemental analysis and X-ray mapping analysis have been used to examine the coated specimens.

The porosity of the CNT-Cr₂O₃ composite coatings was found to be decreasing with the increases in CNT content, and hardness has been found to be increasing with increase in percentage of CNT in the composite coatings. The CNT were able to increase hardness by approximately 17 per cent. It was found that the CNT were uniformly distributed throughout Cr₂O₃ matrix. The CNT were found to be chemically inert during the spraying process.

It must be mentioned here that studies related to fabrication of HVOF sprayed CNT reinforced Cr₂O₃ composite coatings on T22 boiler tube steel are not available in the literature. Hence, present investigation can provide valuable information related to fabrication and properties of CNT reinforced coatings on boiler steel.

This paper aims to investigate the high temperature corrosion behaviour of ZrO₂-reinforced Cr₂O₃ matrix-based composite coatings on ASTM-SA213-T-22 steel at 900°C in molten salt environment. The different coatings were deposited by high velocity oxy fuel (HVOF) method.

Hot corrosion studies were conducted in simulated boiler environment in silicon carbide tube furnace at 900°C for 50 cycles on bare and HVOF-coated boiler steel specimens. Each cycle consisted 50 h of heating in the simulated boiler environment followed by 20 min of cooling in air. The weight change measurements were performed after each cycle to establish the kinetics of corrosion using thermogravimetric technique. X-ray diffraction and scanning electron microscopy techniques were used to analyse the corroded specimens.

The addition of 20 Wt.% ZrO₂ in Cr₂O₃ helped reduce corrosion rate by 89.25% as compared to that of uncoated specimen. The phase analysis revealed the presence of Cr₂O₃ and ZrO₂ phases in composite coating matrix, which may have prevented the base metal from interacting with the corrosive elements present in the highly aggressive environment and thus had increased the resistance to hot corrosion.

It should be mentioned here that high temperature corrosion behaviour of thermally sprayed ZrO₂–Cr₂O₃ composite coatings has never been studied, and to the best of the authors’ knowledge, it is not available in the literature. Hence, present investigation can provide valuable information for application of ZrO₂-reinforced coatings in high temperature fuel combustion environments.

Molten sulphate-vanadate induced hot corrosion is the main reason of failure of boiler tubes used at high temperatures in thermal power plants. The hot corrosion can be encountered by applying thermal spray coatings on the alloy steels. In this perspective, this paper aims to attempt to investigate the effect of carbon nanotubes reinforcement on Cr₂O₃ composite coatings on hot corrosion behaviour of ASTM-SA213-T22 steel in a corrosive environment of Na₂SO₄ – 60%V₂O₅ at 900^°C for 50 cycles.

The coatings have been deposited with high velocity oxy fuel process. The samples were exposed to hot corrosion in a Silicon tube furnace at 900^°C for 50 cycles. The kinetics of corrosion behaviour were analysed by the weight gain measurements after each cycle. Corrosion products were analysed with X-ray diffraction, scanning electron microscopy, energy dispersive and cross-sectional analysis techniques.

During investigations, the carbon nanotubes (CNT) reinforced Cr₂O₃ composite coatings on T22 steel were found to provide better corrosion resistance in the molten salt environment at 900^°C. The coatings showed lower weight gain along with formation of protective oxide scales during the experiment. Improvement in protection against hot corrosion was observed with increase in CNT content in the coating matrix.

The addition of CNT has resulted in reduction in porosity by filling the voids in chromium oxide coating, with interlocking of particle and has blocked the penetration of corroding species to enhance the corrosion resistance of the composite coatings. The corrosion rate was found to be decreasing with increase in CNT content in coating matrix.

It must be mentioned here that high temperature corrosion behaviour of thermally sprayed CNT-Cr₂O₃ composite coatings has never been studied, and it is not available in the literature. Hence, present investigation can provide valuable information for application of CNT-reinforced coatings in high temperature fuel combustion environments.

The purpose of this paper is to examine the mechanical characteristics and optimization of wear parameters of hybrid (TiO₂ + Y₂O₃) nanoparticles with Al matrix using squeeze casting technique.

The hybrid aluminium matrix nanocomposites (HAMNCs) were fabricated with varying concentrations of titanium oxide (TiO₂) and yttrium oxide (Y₂O₃), from 2.5 to 10 Wt.% in 2.5 Wt.% increments. Dry sliding wear test variables were optimized using the Taguchi method.

The introduction of hybrid nanoparticles in the aluminium (Al) matrix was evenly distributed in contrast to the base matrix. HAMNC6 (5 Wt.% TiO₂ + 5 Wt.% Y₂O₃) reported the maximum enhancement in mechanical properties (tensile strength, flexural strength, impact strength and density) and decrease in porosity% and elongation% among other HAMNCs. The results showed that the optimal combination of parameters to achieve the lowest wear rate was A3B3C1, or 15 N load, 1.5 m/s sliding velocity and 200 m sliding distance. The sliding distance showed the greatest effect on the dry sliding wear rate of HAMNC6 followed by applied load and sliding velocity. The fractured surfaces of the tensile sample showed traces of cracking as well as substantial craters with fine dimples and the wear worn surfaces were caused by abrasion, cracks and delamination of HAMNC6.

Squeeze-cast Al-reinforced hybrid (TiO₂+Y₂O₃) nanoparticles have been investigated for their impact on mechanical properties and optimization of wear parameters.

The purpose of this paper is to evaluate the effect of titanium oxide (TiO₂) and yttrium oxide (Y₂O₃) nanoparticles-reinforced pure aluminium (Al) on the mechanical properties of hybrid aluminium matrix nanocomposites (HAMNCs).

The HAMNCs were fabricated via a vacuum die-assisted stir casting route by a two-step feeding method. The varying weight percentages of TiO₂ and Y₂O₃ nanoparticles were added as 2.5, 5, 7.5 and 10 Wt.%.

Scanning electron microscope images showed the homogenous dispersion of nanoparticles in Al matrix. The tensile strength by 28.97%, yield strength by 50.60%, compression strength by 104.6% and micro-hardness by 50.90% were improved in HAMNC1 when compared to the base matrix. The highest values impact strength of 36.3 J was observed for HAMNC1. The elongation % was decreased by increasing the weight percentage of the nanoparticles. HAMNC1 improved the wear resistance by 23.68%, while increasing the coefficient of friction by 14.18%. Field emission scanning electron microscope analysis of the fractured surfaces of tensile samples revealed microcracks and the debonding of nanoparticles.

The combined effect of TiO₂ and Y₂O₃ nanoparticles with pure Al on mechanical properties has been studied. The composites were fabricated with two-step feeding vacuum-assisted stir casting.